From Rob - Names to keep in mind while doing our research:
James Reddish- Alexander is a witness to his son's will
Robert Crawford- associate of John Scott
John Waugh- Anglican minister from Tyrone Ireland- spent time in Scotland before immigrating
Matthew Steele- merchant in Virginia, Maryland, Barbadoes- mentioned in will of Samuel Sinckler- 1677
John Wilson- Steele's partner in Maryland and Barbadoes- mentions Sinclairs in his apparent Barbados will
Thomas Monteith of Glasgow- Thomas Sinclair indentures to pay a debt to him in Stafford County, Virginia
John Douglas- son of Douglas of Mains- emigrates to Virginia in 1655- Isaac marries his descendant, Letitia. (later - The (Douglas of) Mains in question was southeast of Glasgow. I believe, in Lanarkshire.)
William Stone- listed as a tither in Alexander's household 1724
James Ewell- a neighbor and friend of Alexander
Robert Kingsbury- business partner of John Sinclair of Maryland- 1650s
Ninian Beall- one of the indentures who John Sinclair claims headrights for
Ship Mary of Waterford- a John Sinclair pays her bond in Maryland- 1683
Bogle and Co. vs Sinclair's heirs, 3 Feb, 1767- Special Imparlance- Loudoun County
Updated by Rob -
Boyd family - I know that they were among the ayrshire families to colonize Ireland.
Waugh - also a pronounciation of Veatch and I know that there is an ayrshire family by that name that was active in Virginia and connected with some rleated families.